If you're having trouble establishing a mind-muscle connection with your triceps then begin the workout with something that puts the muscle into a shortened position, and work isometrics (holding the contraction) to help with that. Try a pushdown variation. My favorite for this is the reverse-grip pushdown.
Make a concerted effort to roll your knuckles back towards your body and hold that for a 2-3 count for 3-4 sets.
The Bent-Over Barbell Row is a great exercise, but hardly anybody does it correctly. Most people look like they're having relations with a small farm animal when they do BB rows. Hence the Incline Bench Dumbbell Row.